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Dess-Martin periodinane is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. This periodinane has several advantages over chromium - and DMSO-based oxidants that include milder conditions, shorter reaction times, higher yields, and simplified workups.
Periodinanes are chemical compounds containing hypervalent iodine. These iodine compounds are hypervalent because the iodine atom in it contains more than the 8 electrons in the valence shell required for the octet rule. When iodine is complexed with a monodentate electronegative ligand such as chlorine, iodine compounds occur with a +3 oxidation number as iodine(III) or λ 3-iodanes or as a +5 oxidation number as iodine(V) or λ 5-iodanes.
Dess-Martin Periodinane ... CAS: 87413-09-0: FW: 424,16: Melting point: 133-134 o C: Merck: 13,2950: Beilstein: 4548207
Caution: Compounds 1 and 2 are heat- and shock-sensitive compounds, showing exotherms when heated (>130°C). All operations should be conducted behind an explosion shield.
Dess-Martin periodinane. The Dess-Martin periodinane (DMP) is commercially available and decomposes only slowly. But DMP is heat- and shock-sensitive, and shows an exotherm when ...
Dess-Martin Periodinane ... CAS: 87413-09-0: The Dess-Martin periodinane (DMP) is a mild, versatile reagent for selective oxidation of primary and secondary alcohols to aldehydes ...
Image:Dess-Martin periodinane.svg - Wikimedia CommonsFile history. Click on a date/time to view the file as it appeared at that time.
Media in category "Dess-Martin periodinane" The following 5 files are in this category, out of 5 total.
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